Rare Earth Recycling Magnets: What are rare earth magnets?

What are rare earth magnets?

Rare earth magnets are magnets that contain rare earth elements. We've already covered these, but let's sum them up once more: Scandium, Yttrium, Lanthanum, Cerium, Praseodymium, Neodymium, Promethium, Samarium, Europium, Gadolinium, Terbium, Dysprosium, Holmium, Erbium, Thulium, Ytterbium and Lutetium. Bold elements are used for rare earth magnets. The other chemical elements are applied outside of the recycling industry.

A Samarium-Cobalt is a ferromagnetic compound of one of two kinds of commercially available rare earth super-magnets. It's normally a bit cheaper than its counterpart, namely the Neodymium-magnet. In the future, there might even be a mega-magnet made out of Holmium, but research is still on the way.

NIB Rare Earth Magnet
NIB-Magnets are currently the most popular kind of magnet in the recycling industry.

Samarium-Cobalt

When buying a magnet like mentioned above, it is always important to pick the right alloy. Should you need high resistance to demagnitization and decent stability under high temperatures, it is wisest to pick the Samarium-Cobalt compound. You have this available in two 'series' or scales, namely the 1:5 - and 2:17 Samarium to Cobalt ratio. The ratio means that there is either 1 Samarium atom for 5 Cobalt atoms or 2 Samarium atoms for 17 Cobalt atoms. Another advantage next to demag resistance and high thermal stability is its resistance to oxidation. A disadvantage of a Samarium-Cobalt magnet is that it may facture under cold temperatures. It also inclined to chip and crumble faster than a Neodymium magnet. The dicisive fact that makes this magnet less attractive than its counter part is the cost and the fact that its magnet strength is lower.

Neodymium

A NIB-Magnet (abbreviated: Neodymium-Iron-Boron) is the most popular kind of super-magnet available. The reason for that lies in the high magnetic strength and (relatively) low cost. It's an alloy with Neodymium, Ferrum, Boron, but also with Aluminium, Nibium and Dyprosium. As opposed to the SmCo-magnet, the Nd-magnet is prone to oxidate. For that reason, a Nd-magnet is always coated with Tin, Nickel, Zinc or even gold. NIB-magnets used to be quite expensive to produce, yet they have less expensive since the 90's.

Needless to say, most recycling industry magnets are NIB magnets.


Holmium-Yttrium

First this: as far as I know, there isn't a Holmium-Yttrium magnet commercially available. Google results are quite fuzzy about this though. Despite knowing that Holmium has the highest magnetic moment of 10,6 µB, it hasn't found real commercial use as recycling magnet.

I'll look into Holmium magnets every now and then and provide you with information as soon as I can find it.

Rare Earth Recycling Magnets: The Chemical Elements

What are rare earth elements?

Rare earth elements is a set of chemical elements on the periodic table. Scandium, Yttrium, Lanthanum, Cerium, Praseodymium, Neodymium, Promethium, Samarium, Europium, Gadolinium, Terbium, Dysprosium, Holmium, Erbium, Thulium, Ytterbium and Lutetium are the rare earth elements. You can find this on your periodic table.

Rare-earth-magnets
Source: Pixabay (CC0)


21    Sc    Scandium is rarely used due to the lack of predictable, safe and longterm commercial application. It used to be employed in aerospace and has recently received more attention for its use as an aluminium alloy (less than 1% of Scandium inside). Scandium-Zirkonia is also used as an electrolyte in SOFC (solid oxide fuel cells).

39    Y    Yttrium has many uses and functions. Its most important use is the creation of the Europium phosphor, which is used in CRT and LED screens to produce red light. An Yttrium-Iron garnet is used in microwaves (as a filter), as an audile transducer / transmitter, in a Faraday Rotator and for MOI (magnetic optical imaging) in a superconductor. Yttrium is also used in small amounts to increase the strength of aluminium alloys.

57    La    Lanthanum alose finds its use in many items.

Here are some of them: 1. under the term phoslock, it gets rid of phosphates in lakes and pools. 2. Lanthanum oxide is used in optics for camera - and telescope lenses due to its high refractive index and low dispersion. 3. Mischmetal - also called Ferrocerium or Auermetall - is an alloy with 50 % Cerium and 25 % Lanthanum inside. It's used to create sparks (flint spark lighter).

Let's keep the other applications of this rare earth element short and simple: energy conservation system, electron microscopes, scintillator, radiometric dating and carbon arc lamps.


58    Ce    The most abundant rare earth element available, Cerium, has numerous commercial applications. Flints, permanent magnets, Tungsten electrodes, carbon-arc lighting, petroleum catalyst and as a component in screens.


59    Pr    Finally we have an element which is used for recycling industry magnets, namely Praseodymium. A certain share of Praseodymium is in high power magnets together with Neodymium, Iron, Boron and Dysprosium. We'll cover this in greater depth in another Q&A. What's also important to know: the discoverer of Didymium - which is composed of Neodymium and Praseodymium - thought that the composition was actually one element. Carl Auer von Welsbach actually isolated both rare earth elements and named them Neodidymium and Praseodidymium, which was later shortened.

Imagine Ned Flanders saying "Praseodidymium magnet".
Would probably sound something like "Praseodiddeledidium Magnereeno".

Other uses besides recycling magnets: 3-8% part of Mischmetal, strengthening of metal (dopant), optical magnifying, Weldergoggles and Glasblowergoggles, flint rock, enamel colouring and as glass colouring.


60    Nd    Neodymium - as a free element - never occurs in nature, as it oxidizes when it comes in contact with air. However, it can be found within ores like bastnäsite and monazite. It functions as the main compound of rare earth high power recycling magnets but has other distinct utilizations. For example, Neodymium glass is used as a rear-view mirror to minimize glaring from drivers behind you. It is also used - like other rare earth elements - as a glass colouring and enamel colouring. It also finds its application in lasers.


61    Pm    Promethium - also written as Prometheum - was first separated in 1945 by the Oak Ridge National Laboratory from a byproduct of nuclear fission. In fact, that's still a method of obtaining Promethium today. As you might suspect, Prometheum is radio-active and therefore harmful to humans. It's used in nuclear batteries, luminous paint, missiles and possibly has a future in portable x-ray devices for space exploration.

Promethium is the least abundant of the lanthanides.


62    Sm    Samarium emerges as a profitable high-power magnet in combination with Cobalt. It isn't stronger than a Neodymium (and Boron Iron Dysprosium Aluminium) alloy. Nevertheless it makes quite the powerful magnet. Sometimes it is preferred over the Neo-Magnet as the costs are a lot lower. I'll create a separate article for magnets that depend on rare earth element.

Other uses are as a control rod in nuclear reactors, radioactive dating, catalysis of chemical reactions, x-ray laser, maser, cancer treatment and in the engine of solar-powered vehicles.


63    Eu    Europium puts the 'rare' in rare earth elements, as it is the scarcest element in the entire universe. It doesn't have a lot of (profit-making) application. Like a lot of other elements, Europium is used as a doping agent in (some) optical equipment. As an oxide, it finds its use as red phosphor in computer and television screens. Another application of Europium I know of are drug tests, in which it determines what amount of any kind of drug is present in the blood of the 'donor'. I've linked to a pdf document below that serves as an example.

Source: https://tools.thermofisher.com/content/sfs/manuals/Eu_Instrument_Control_AppNote_12Nov10.pdf


64    Gd    Gadolinium cannot be found in its pure form in nature but is abundantly available in bastnasite and monazite. The founder of the element - Johan Gadolin - first found it in an ore he named after himself, namely Gadolinite. When you'd expect Gadolinite to be filled with Gd, then you'd be wrong. It's quite ironic that the nameholding ore only has tiny amounts of Gadolinium.

You can find Gadolinium in SOFCs (electrolyte), x-ray devices, optoelectronics, microwaves, nuclear reactors, nuclear submarines, MRI scanners and in TV screens (green phosphor).


65    Tb    Terbium is partially relevant as it is an additive in the Neodymium power-magnet. Other applications include as crystal stabilizer in fuel cells, as green phosphor in screens, for trichomatric lighting technology and as a doping agent for certain materials. Together with Dyprosium, it is used in Terfenol-D (more info on that in the next element).


66    Dy    The element 'Dysprosium' is an additive of Neod.-recycling magnets as well. We'll expand on this in another section. Next to its function as a super-magnet, data storage applications employ a different advantageous attribute from this element, namely its magnetic susceptibility. It also puts the 'D' in 'Terfenol-D'... literally. Terfenol-D is a magnetostrictive material that is outrun by another compound called Galfenol (without the -D). Due to its high thermal neutron absorbtion, it is also used for making control rods in nuclear reactors.


67    Ho    Holmium is also a rare earth element with magnetic properties that are not yet discovered as of now. That makes this element my personal favourite rare earth element. Try to google "holmium magnetic properties" and you'll only find scholarly articles that imply that research is on the way or broad very broad wikipedia-like descriptions of Holmium as an element (its history, its physical/atomic/chemical properties, health benefits/empediments, etc.).

Anyway, it is my favourite element as it may contribute to the development of even more powerful magnets.

Holmium is used for lasersurgery due to low tissue penetration rates. A thulium laser is the only laser I know of that is more shallow.

68    Er    The chemical element Erbium with atomic number 68 isn't found in nature as a pure element. Fibre-optic-cables and other technology that rely on on fiber-optic make use of Erbium as a dopant.

Other uses: Laser amplification, vanadium steel, glass colouring, cryocooling instruments, laser surgery and laser enamel treatment and as a porcelain colourant.


69    Tm    Thulium is an element from the set of lanthanides. It isn't employed in lots of applications and items, due to its rarity and therefore due to its high price. There are a few field of expertise where Thulium is unsubstitutable: laser surgery. It's also used in x-ray machines.


70    Yb    Ytterbium is a silver coloured, soft metal. If it's put under high enough pressure, it can function as a semiconductor device. In nature, this element cannot be found in its pure form. It mostly appears in monazite, where it is mostly mined from.

Ytterbium is a component in many industries and products. Here are some broader categories in which Ytterbium is used: metallurgy, solid-state-laser / DCF-Laser, the world's most reliable atom-clock, medicine, doping agent in steel and it has been used once as a toothfilling alloy in the Dental prosthesis industry.


71    Lu    The element Lutetium is last in the series of Lanthanides. It has a bright silver colour and is quite hard and dense. There aren't copious amounts readily available in the earth's crust, but I wouldn't call it rare either. Problems do not arise with obtaining Lutetium containing ores like monazite, but with the separation of Lutetium from other chemical elements. This fact still makes pure Lutetium very expensive (ca. 1/4th price of gold).

Probably due to its high price, there still aren't a lot of applications for Lutetium. A very specific application of this element is Lutetium-Hafnium radiometric dating method, which is used to determine the age of rocks (or meteorites). Other uses are as medicine, catylyst, dopant and in magnetic bubble memory devices.

Grate magnet

A round or rectangular grill or grating is placed within a duct in order to filter ferromagnetic components from waste stream. This recycling tool comes in many shapes and sizes. An optional self-cleaning mechanism enables more efficient putthrough and less manpower that goes into otherwise remedial tasks. The fact that it takes up only little space makes this an important add-on that suits almost all recycling factory.

granulate
Source: Pixabay (CC0)


If you want to read more about grate magnets, feel free to visit our page by clicking here.

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Hump magnet

A hump magnet is basically a duct with one or more plate magnets inside, which are placed in a certain angle, so the magnets catch ferromagnetic parts. The material is fed through a chute on top of the machine. As the waste stream doesn't drop down in free-fall but impacts on the plate magnets the parts are either collected  on the first or the second magnet. It is able to separate and process low to high throughput.

doublehump
Source: Pixabay (CC0)

Please click this link for more information regarding hump magnets.

The Drum Separator

Fe Drum Separator


Contrary to the usual separators subsequent generation with wet drum separators assigned to use specific magnet assemblies, which in turn judged upgrade to a 120% within the normal magnetic force list in the entire operating range in which the actual slurry goes.

A drum separator successfully enrichment in terms of iron ore and also heavy press for decades. Everywhere in terms of iron ore processing many decent machines have putthrough which is usually up to 28 to/h.
The effect is not only a kind of decrease in the cost optimization of products, but also with an increase in volume and restore performance and displays each fund and operational cost savings.
 
It is suitable for incredibly fine-grained ingredients (<10µm). It enriches the emphasis of the large gradient permanent magnet filtering to a extremely overflowing waste. In more compact throughput rates, in addition, it successfully washes dirtied degreasing fluids as well as other fluids. It's powerful neodymium magnetic technique makes sure dependable splitting up intended for these feed styles as well.

Your water streams by way of a semi-circular splitting holding chamber down below some sort of steel drum to be able to that this magnetisable particles are generally limited. A new tube comprising permanent magnetic dvds placed inside drum makes this solid, high-gradient permanent magnet discipline. Your particular everlasting magnets produce in particular large discipline gradients, which might be important intended for prosperous splitting up, while is the event along with all permanent magnet separators. Through twisting this drum, this filtering dessert is elevated from the slurry plus the permanent magnet discipline.


Non Ferrous Drum Separator

The new generation Non-Ferrous Metal Separator ensures more profitability for processing fine fractions! The machine provides the economic basis for every recycling system involving the extraction of non-ferrous metals. Thanks to its reliability and long service life, it ensures an optimal operating result over the long term.

After optimization of the rotational speed, the non-ferrous metal separator now achieves even better results when separating non-ferrous metals from fine fractions.

See the benefits of operating at speeds of up to 4,000 rpm and a field frequency up to 1.27 kHz, the new recycling machines are capable of increasing its extraction rate by 20 to 30 per cent compared with a non-ferrous metal separator operating at 2,600 rpm. The result is, however, strongly dependent on the material involved. Depending on the grain size, the extraction rate increases with increasing speed and a field frequency, up to a maximum value. This maximum is reached at a speed of 3,500 - 4,000 rpm. It is possible to significantly increase the extraction of non-ferrous metals from automotive shredder residue as well as slag for particle sizes of 0 - 4 mm and 4 - 8 mm as recent installations have shown. This comes at no compromise to the quality of the non-ferrous product which remains at highly sellable purity levels.


Processing fine material

Most Non-Fe-Separators now offer a complete system concept without the need to add any interfaces, installations or control equipment. It is the complete solution for increased efficiency, control and adjustment needed in the sorting of metal particals. The processing of grainy material has become a popular recycling business in recent years. With separate magnetic drums and magnetic head pulleys, and the non-ferrous separator, many manufacturers have been offering successful solutions in this field for several years.
 
What makes the these machines extraordinary is the fact that it unites into a single, compact unit. a drum separator works best in the range of 1 to 25 mm (1/25 to 1 inch) – a range where most eddy current systems have trouble recovering non-ferrous material.


The machine is commonly used in sodium processing plants, the building materials industry and the industrial minerals sector. It is ideal for sorting free flowing bulk materials in the fine-grained particle range from 200 μm up to several millimetres.

Eddy Current Separator

We've already covered the separation of ferrous material from a waste stream on a conveyor belt using a suspended electro magnet or a suspended permanent magnet. The next magnetic sorting machine of the recycling industry I'd like to cover is a nonferrous separating machine.

Let's say we have an aluminium can recovery factory. Now imagine a conveyor belt filled with plastic bottles and cans. Using an eddy current separator, it is possible to attract or reject metallic nonferrous objects like aluminium.

Can Recycling
Source: Pixabay (CC0)

Eddy Current Separator  - Read more...

Suspended permanent magnets and electromagnets


Suspended electromagnetic separators or permanent magnetic separators come in many sizes and with a lot of features. We'll try to cover the different options available. First of all you have (cheap) permanent and (more expensive) electromagnets. Suspended magnets hang above a conveyor belt and can be self-cleaning. The self-cleaning mechanism makes use of a reject belt. This can be in-line or cross-band. Your choice depends on the line you have or the line you're planning to build.

If you want to read more about this subject, feel free to visit our page. In the future, we will also provide you with links to new and used recycling machines.


electromagnet
Source: Pixabay (CC0)

Suspended electromagnet and permanent magnet

Soon to be the biggest blog on Recycling Magnets

Our aim is to inform propriators of recycling plants about the wide range of ferrous and non ferrous magnetic separating machines available on the market. There are so many options and there is no such thing as "the best magnetic sorting machine". It all depends on the recyclates, on the plant line and its machinery, ie. the shredders, balers, conveyors and so forth, the budget and ofcourse the preferences of the holder of the plant. That being said, it is important to be well informed with regards to this very specific device within a whole system of machines.

please wait
Source: Pixabay (CC0)
 

Let's begin with asking ourselves what magnets actually do within a factory.

The goal of any recycling factory is to convert junk into useful reusable material. An example may explain what makes separating machines an invaluable and treasured asset in a plant line. Raw materials of a computer consist of lead, nickel, platinum, silver, tantalum, cobalt, neodymium, tin, copper, aluminum, gold and palladium. The computer in its original form is just scrap. However, if you separate all the substances that your PC or laptop consist of, then it's worth a lot more.

A wide range of different kinds of magnets are used for separating ferrous and non ferrous material. All of them use different techniques and work flows. In the menu on the right side of the blog, you'll find a range of categories that are used in the industry. In the introduction I've said that the right machine depends on the recycling line you have.